two liquids A and B have vapour pressure in the ratio 2:3 at a certain temperature .Assuming that A and B forms an ideal solution and ratio of mole fraction of A and B in the vapour phase is 1:3,then the mole fraction of A in the solution at the same temperature is

Total vapour pressure = 2 + 3 = 5Mole fraction of A = 14 and mole fraction of B = 34  (moles are in the ratio 1 : 3)pA = XA × PTot     = 14 × 5 = 1.25pB = XB × PTot    = 34 × 5 = 3.75Thus the mole fraction of APAPB α XA XA = 1.253.75 = 13

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