Q). Diamond has ZnS type. Edge length 100 pm. Calculate bond length of CC bond and effective number of carbon atoms in one unit cell.

The solution is as follows:

ZnS has FCC lattice. Thus,

    4r = 2a r = a22=35 pmAnd thus, bond length 2r = 2×35 = 70 pmNumber of atoms in FCC = 18×8+12×6 = 4

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