Is (CH3)3 a nucleophile or electrophile? And why?
Dear Student,
(CH3)3C+ is a positively charged electrophile. This is a tertiary carbocation which has an electrophilic centre (C+) is stabilized +I effect of the 3 methyl groups There is a deficiency of electrons at the carbon centre and hence it will behave as a electrophile. This is formed when when the leaving group is more electronegative compared to carbon or in the presence of an acid
(Br more elctronegative compared to C)
(CH3)3C- can also be formed when the leaving group is less electronegative or in the precence of a base . (CH3)3C- will be weak nucleophile because it has e- rich C centre. It will be weak due to the destabilization of 3 methyl groups.
( base will abstract the proton).
The behaviour of (CH3)3C will depend on the path from which it is formed.
Regards!
(CH3)3C+ is a positively charged electrophile. This is a tertiary carbocation which has an electrophilic centre (C+) is stabilized +I effect of the 3 methyl groups There is a deficiency of electrons at the carbon centre and hence it will behave as a electrophile. This is formed when when the leaving group is more electronegative compared to carbon or in the presence of an acid
(Br more elctronegative compared to C)
(CH3)3C- can also be formed when the leaving group is less electronegative or in the precence of a base . (CH3)3C- will be weak nucleophile because it has e- rich C centre. It will be weak due to the destabilization of 3 methyl groups.
( base will abstract the proton).
The behaviour of (CH3)3C will depend on the path from which it is formed.
Regards!