A certain ideal gas has Cv.m = a + bT, where a = 25.0 J/(mol. K) and b = 0.03 J (mol. K2). Let 2 mole of the gas go from 300 K and 2.0 litre volume to 600 K and 4.0 litre. ΔSgas is
(1) 32.08 J/K               (2) –12.08 J/K            (3) 64.17 J/K                (4) None of these

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