Work done in taking an electron around a proton in a circular loop is 0. Should the proton necessarily be at the centre of the loop?
Work done in moving a particle in a circular orbit would always be zero, as the net displacement is zero.
Let's take the classical picture...
The electron needs to revolve around the center of mass of the electron-proton system, which incidentally would be inside the proton itself as the mass of protons is quite high compared to that of electron. This is analogous to the Earth-Moon system in which the center of mass of the system is inside the earth.
Now, the electron will always move in such a way (which proton at its center) unless acted upon by some external force.