why is oxidation no. of oxygen in OF2 n O2F2 +ive?
Fluorine predominantly exhibits -1 oxidation state in almost all it compounds. In both OF2 and O2F2, its oxidation number is -1. Using this, we will calculate the oxidation state of oxygen in both the compounds. The overall charge in both these compounds is zero. So when we calculate the charge on oxygen in OF2and O2F2, it comes out to be +2 and +1 respectively. You can also calculate it as follows:
OF2
Let the oxidation number of oxygen be z. As there is no overall charge on the molecule, therefore we have
z + 2 (-1) = 0
This gives z = 2
Thus the charge on oxygen in OF2 is +2.
O2F2
Let the oxidation number of oxygen be z. As there is no overall charge on the molecule, therefore we have
2z + 2 (-1) = 0
This gives 2z = 2
or z = 1