what do you mean by all these definitions

Use at with the name of a place when you think of it as a point.

Use on with the name of a place when you think of it as a surface.

Please follow the link given below:

https://www.meritnation.com/ask-answer/question/what-do-you-mean-byuse-at-with-the-name-of-a-place-when-you/prepositions/5548709

'On' is used when we think of a place as a surface, that is when we denote the upper layer of something.

I was sitting on a bicycle, while she was sitting in a car.

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