Read the following passage and answer the questions that
follow:



How can you distinguish between CH3CH2 NH2 and
(CH3CH2)2NH by Hinsberg test?
 

Solution:

  • Benzenesulphonyl chloride (C6H5SO2Cl) (known as Hinsbergs reagent) reacts with 1° and 2° amines to form sulphonamides.With primary (1°) amine it forms a product which is soluble in alkali
  • With secondary (2°) amine it forms a product which is not soluble in alkali.

    ​​​​​​​​​​​
    ​​​​
    ​​​​​No reaction with tertiary (3°) amines

This reaction is used for the distinction of 1°, 2° and 3° amines.

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