One litre of mixture of CO and CO2 is passed through red hot charcoal in a tube. The new volume becomes 1.4litres. Find out percentage composition of the mixture b volume. All measurements are made at same P and T.
Equation of the reaction:
CO2 + C = 2CO
According to equation, when 1 litre of CO2 reacts with 1 mol of coke, twolitres of CO are formed. Our mixture of gases has volume 1.4 L. Thus it is
composed from CO and non-reacted CO2.
If x litres of CO2 are reacted, 2x liters of CO are formed. Total volume ofmixture is the sum of CO2 and CO volumes:
V(mixture) = V(new volume CO2) + V(CO) = 1.4 L
V(new volume CO2) = V(initial volume CO2) - V(reacted CO2) = (1 - x) L
V(CO) = 2x
So, we have equation:
1.4 = 1 - x + 2x
The solution is x = 0.4 L
Thus, the mixture consist from 1-0.4=0.6 L of CO2 and 2*0.4=0.8 L of CO (iii)
Answer: (iii)
The composition of product is 0.6 ltr of CO2 and 0.8 ltr of CO.
CO2 + C = 2CO
According to equation, when 1 litre of CO2 reacts with 1 mol of coke, twolitres of CO are formed. Our mixture of gases has volume 1.4 L. Thus it is
composed from CO and non-reacted CO2.
If x litres of CO2 are reacted, 2x liters of CO are formed. Total volume ofmixture is the sum of CO2 and CO volumes:
V(mixture) = V(new volume CO2) + V(CO) = 1.4 L
V(new volume CO2) = V(initial volume CO2) - V(reacted CO2) = (1 - x) L
V(CO) = 2x
So, we have equation:
1.4 = 1 - x + 2x
The solution is x = 0.4 L
Thus, the mixture consist from 1-0.4=0.6 L of CO2 and 2*0.4=0.8 L of CO (iii)
Answer: (iii)
The composition of product is 0.6 ltr of CO2 and 0.8 ltr of CO.