On heating Pb(NO3)2 a brown gas is evolved which undergoes dimerisation on cooling. Which is that gas

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The gas is no2
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NO2
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The gas so evolved is NO2 which dimerises to give N2O4
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Pb(NO3)2 --->PbO2+2NO2
​NO2 gas is released when lead nitrate is heated which is brown in colour.

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